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I'm currently using the automatic image synchronization option with Onedrive. But unfortunately all images are synced to the wrong account (account with 7GB of space instead of account with 25GB).
I'm not talking about Onedrive app, but feature built into Windows Phones
The built in feature always uses the Microsoft Account for this. You can change this only changing the entire Microsoft Account of the phone.
Unfortunately you would have to reset the phone and start again as it links to the account you entered when you set up the phone
Reset the phone and to transfer apps try this answer here and this forum.
